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Fe3O4/ZIF-8 Nanocomposite Removes Copper and Arsenic to Avoid Livestock Industry Contamination
Date: 2021/04/23 Author: WU Qingchuan

With the development of livestock husbandry, a large amount of copper (Cu) and arsenic (As) ions are being released into water and soil with swine urine, because Cu(II) and As(III) are commonly added into fodder to promote the growth of swine. Cu and As ions are easily absorbed by crops, and then accumulate in human body when the crops are consumed, resulting in severely harmful effects on health. This is one of the key issues that limit the sustainable development of livestock husbandry and agriculture. Therefore, it is imperative to develop a new technology to remediate Cu/As-contaminated water, soil, and swine urine.

Recently, a team led by Prof. WU Zhengyan from Institute of Intelligent Machines, Hefei institutes of physical science, managed to develop a nanocomposite to removal Cu(II) and As(III) simultaneously. They synthesized the nanocomposite using Fe3O4 microspheres and ZIF-8 through a coprecipitation method, and named the obtained nano system as FZ.

In this research, scientists investigated the removal efficiency of FZ on Cu(II) and trivalent arsenic (As(III)) in water under different conditions to obtain the optimal FZ named as FZ4. Then, They studied the removal performance of FZ4 on Cu(II) and As(III) in swine urine aqueous solution and soil. The interactions among FZ4, Cu, and As were analyzed to reveal the mechanism on Cu(II) and As(III) removal. Additionally, pot experiments were performed to prove the removal performance of FZ4 for Cu and As.

"It turns out that FZ4 could effectively reduce the uptake of Cu and As by zebrafish and water spinach." said WU Zhengyan, a scientist of biology. 

This work provided a method to remove Cu(II) and As(III) simultaneously in water, soil, and swine urine, which may have a high application value in reducing Cu(II) and As(III) pollution.

This research was supported by the Science and Technology Service Program of Chinese Academy of Sciences, the National Key R&D Program of China, the Key R&D Program of Ningxia Province, the National Natural Science Foundation of China, the Fundamental Research Funds for the Central Universities.

Link to the paper: Fabrication of Fe3O4/ZIF-8 nanocomposite for simultaneous removal of copper and arsenic from water/soil/swine urine

Schematic illustration of mechanism. (Image by WU Qingchuan)

Contact:

ZHAO Weiwei
Hefei Institutes of Physical Science (http://english.hf.cas.cn/)
Email: annyzhao@ipp.ac.cn

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