Recently, a research team led by Prof. CHEN Changlun from Institute of Plasma Physics, Hefei Institutes of Physical Science of Chinese Academy of Sciences, studied Cu(I)Cu(II)-BTC, a kind of hydrogen isotope separation material and proved its crucial role in tuning quantum sieving without a complex structural design, which provided a new strategy for the intelligent design of highly efficient isotope systems.
The result was published in ACS Applied Materials & Interfaces.
High pure deuterium (D2) is an important industrial and scientific gas, which has been widely used as an irreplaceable raw material, neutron moderator, isotopic tracer, and in other fields. Despite the huge demand for it, the mole fraction of natural deuterium is only up to 0.0156% of natural hydrogen in the oceans. Moreover, D2 and its isotope (H2 or T2) molecules have almost identical classical dimensions, associated with very similar physicochemical properties, and the separation of hydrogen isotope mixtures in high purity has been considered as one of the greatest difficulties and challenges in modern separation technology.
In this study, HKUST-1 crystals in the presence of hydroquinone were reduced to construct Cu(I)Cu(II)-BTC, featured by dual micropore size distribution and mixed-valence of Cu metal, and had been chosen to study H2/D2 separation in detail.
The study showed that unique Cu(I) and Cu(II) coordination network of Cu(I)Cu(II)-BTC could significantly facilitate D2/H2 isotope separation. Density functional theory (DFT) calculations indicated that the introduction of Cu(I) macrocycles in the framework decreased the pore size and further led to relatively enhanced interaction of H2/D2 molecules on Cu(II) sites. The significantly enhanced selectivity of Cu(I)Cu(II)-BTC at 30 K was mainly attributed to the synergistic effect of kinetic quantum sieving (KQS) and chemical affinity quantum sieving (CAQS).
In addition, a large angle of 156° for the O-Cu(I)-O configuration in Cu(I)Cu(II)-BTC exhibited weak binding strength of hydrogen adsorption since the dz2 orbital and small positive of Cu(I) couldn't effectively participate in the hydrogen interaction, and didn't show a strong CAQS effect at above liquid nitrogen temperature.
This research verified the effect of Cu(I) structure in D2/H2 separation. "We believe that this study will provide a new strategy for reasonable design of porous materials with OMSs at highly efficient isotope and gas separation systems," said HU Xiaoyu, first author of the paper.
The above study has been funded by the National Key Research and Development Program of China and the National, Natural Science Foundation of China.
Comparison of the D2/H2 selectivity between the results in the literature and our work. (Image by HU Xiaoyu)
The separation mechanism of D2/H2 mixture in Cu(I)Cu(II)-BTC. (Image by HU Xiaoyu)
Highly Effective H2/D2 Separation within the Stable Cu(I)Cu(II)-BTC: The Effect of Cu(I) Structure on Quantum Sieving